By Gould R.F. (ed.)
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1959) 1501. 232 F . A. Cotton and B. F . G . Johnson, Inorg. Chem. 6 (1967) 2 1 1 3 . 233 D. Hartley, P. A. Kilty and M. J. Ware, Chem. Communs. (1968) 4 9 3 . 246 TRANSITION METAL-METAL BONDS: D . L. KEPERT AND K. VRIEZE indicated a linear structure. The force to be about 1-6-1-7 mdynes/Â. The asymmetric trinuclear structure with constant ki of the O s = O s bond is 2-2 single bonds is 1 -7 mdynes/Â. constants of the metal-metal bonds were estimated 2 05 compound Os3(CO)io(OMe)2 probably has an 2 33 one O s = O s double b o n d (Fig.
Haag, Chem. Ber. 94 (1961) 312. 154 H. Behrens and W. Haag, Chem. Ber. 94 (1961) 320. 155 H. Behrens and J. Vogl, Chem. Ber. 96 (1963) 2220. 156 R. G. Hayter, / . Am. Chem. Soc. 88 (1966) 4376. 157 L. B. Handy, P. M. Treichel, L. F. Dahl and R. G. Hayter, J. Am. Chem. Soc. 88 (1966) 226. 158 W. Hieber, W. Beck and G. Braun, Angew. Chem. 72 (1960) 795. BONDS BETWEEN TRANSITION METAL ATOMS OF THE SAME ELEMENT 233 that the structural relationship between the two isomeric forms is similar to those of 159 C o 2( C O ) 8 « > .
VRIEZE negative charge is delocalized on all four metal atoms. The possible existence of HRe4(CO)7 6 181 and H 2R e 4 ( C O ) i 6 was m e n t i o n e d . 18 Further hydrides which were confirmed by mass spectrometry are HRe3(CO)i4 ° » 183 and the dark red HMn3(CO)io(BH3)2, which was obtained as a by-product of the synthesis 1 8 4 of H 3M n 3( C O ) i 2 . The structure of H R e 3 ( C O ) i 4 is very likely similar to that of 1 8 5 H R e 2M n ( C O ) i 4 . The structure of H M n 3 ( C O ) i 0 ( B H 3 ) 2 is shown in Fig.