Progress in Inorganic Chemistry, Volume 7 by F. Albert (Ed) Cotton

By F. Albert (Ed) Cotton


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They were successful in preparing CF30SF4NF2in a 14y0 yield from the reaction of the three reactants contained in a Monel tube for 7 days a t room temperature. This difluoraminosulfur tetrafluoride derivative proved to be the cis-isomer. The structure will be discussed in Sec. 1V. 3' and it reacts slowly with glass at room temperature. The iminosulfur difluorides are a very interesting group of compounds (60). Metallic cyanides, cyanates, and thiocyanates and organic nitriles and isocyanates yield iminosulfur difluorides from reactions with SF4 (61,62).

6 mm. and a melting point of - 10" (70). A substituted SF4, CF3SF3,undergoes reaction with NzF4 to give CF3SF4NF2(48) in 6 to 8% yield along with SF5NFz. uv CFSSFa + NzF4 --+ CFsSF,NF, + SFbNFz It is obvious that there is fluorine atom production and C-S bond cleavage in the reaction, so the additions of F and NF2 to CFBFI account for the minor component of the reaction, CF3SF4NF2. The NMR spectrum will be discussed in Sec. IV. It is corisistcrit with an 57 SULFUR-FLUORINE CHEMISTRY octahedral structure in which the CF3and NF2 groups are trans to each other.

33, 1278-1280 (1962). 81. Boyd, F. , and J. L. , 57, 170-174 (1958). 82. Giardini, A. , J. E. Tydings, and S. B. Levin, Am. Mineralogist, 45, 217-221 (1960). 83. Barnett, J. , and H. T. Hall, Rev. Sci. , 35, 175-182 (1964). Manuscript received by Publisher November 16, 1364 Progress in Inorgunic Chemistry; Volume 7 Edited by F. Albert Cotton Copyright © 1966 by John Wiley & Sons, Inc. Recent Progress in Sulfur-Fluorine Chemistry BY STANLEY M . WILLIAMSON Department of Chemistry. Universily qf California.

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