Progress in Inorganic Chemistry, Volume 34 by Stephen J. Lippard

By Stephen J. Lippard

This complete sequence of volumes on inorganic chemistry presents inorganic chemists with a discussion board for severe, authoritative reviews of advances in each zone of the self-discipline. each quantity studies fresh development with an important, up to date choice of papers through the world over well-known researchers, complemented by way of special discussions and entire documentation. each one quantity contains a whole topic index and the sequence incorporates a cumulative index besides.

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DOUBLE BONDING BETWEEN HEAVIER GROUP 14 AND 15 ELEMENTS VII. 57 CONCLUSION Although compounds with, for example, P=P, As=As, and Si=Si bonds were postulated as long as a century ago, subsequent structural studies revealed that such species were, in fact, oligomeric. No sustained interest was displayed in double-bonded compounds of the heavier main-group elements until the 1960s, when methodologies began to emerge for the production of transient molecules. It was not, however, until the 1980s that these double-bonded compounds were isolated.

A. H. Cowley, I . E. Kilduff, S. K. Mehrotra. N. C. Norman, and M. Pakulski, J. Chem. Soc.. Chem. 528 (1983). A. H. Cowley. J . E. Kilduff, T. H. Newrnan, and M. Pakulski, J. Am. Chem. ,104. 5820 (1982). A. H. Cowley. J. E. Kilduff, N. C . Norman, M. Pakulski. J. I-. Atwood. and W. E. Hunter, J. Am. Chem. Soc.. 105. 4845 (1983). A. H. Cowley, J. E. Kilduff, M . Pakulski, and C. A. Stewart, J. Am. Chem. Soc.. 105. 1655 (1983). A. H. Cowley. J . G. Lasch. N. C . Norman, and M. Pakulski, Angew'. Chem..

N. C. Norman. M. Pakulski, F. Ando, a n d T . C . Wright, J. Am. Chem. Soc.. /05, 7751 (1983). A. H . Cowley. J. E. Kilduff, J. G. Lasch, N. C. Norman. M . Pakulski, F. Ando. and T. C. Wright, Organomerallics. 3 , 1044 (1984). A. H. Cowley. J . E. Kilduff, J. G . Lasch, N. C . Norman, M . Pakulski. B. R. Whittlesey. J . L. Atwood. and W. E. Hunter, Inorg. , 23. 2582 (1984). A. H. Cowley, I . E. Kilduff, S. K. Mehrotra. N. C. Norman, and M. Pakulski, J. Chem. Soc.. Chem. 528 (1983). A. H. Cowley.

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