Peroxide Chemistry: Mechanistic and Preparative Aspects of by Waldemar Adam

By Waldemar Adam

This selection of thirty articles on study initiatives in all components of peroxide chemistry, i. e. analytical, biochemical, inorganic, natural, organometallic, actual, spectroscopic, and theoretical elements, are the results of a multidisciplinary examine software funded by means of the Deutsche Forschungsgemeinschaft (DFG). The emphasis used to be to lie at the improvement of environmentally appropriate, selective (chemo-, regio-, diastereo- and enantioselectivity) oxidations. One bankruptcy makes a speciality of business functions that have to satisfy either within your budget and ecological calls for to stay aggressive sooner or later. most modern effects at the results of lipid peroxidation in age-dependent illnesses, which diversity from Alzheimer and Parkinson problems to diabetes, rheumatic arthritis, atherosclerosis and cardiovascular illnesses also are awarded.

Chapter 1 Landmarks within the improvement of natural Peroxide Chemistry (pages 1–38): Manfred Schulz
Chapter 1 fresh Advances in Homogeneous Catalyzed Epoxidations utilizing Hydrogen Peroxide or tert.?Butyl Hydroperoxide (pages 39–59): Thomas Kratz and Werner Zei?
Chapter 2 Photoinduced Electron?Transfer Reactions of Alkenes and Azide Anions within the Presence of Molecular Oxygen: Formation of 1,2?Azidohydroperoxides and Use As Oxygen?Transfer Reagents (pages 60–77): Axel G. Griesbeck, Jorg Steinwascher and Thomas Hundertmark
Chapter three Preparative Use of Peroxidic Oxidants for Oxygen?Transfer Reactions (pages 78–112): Waldemar Adam, Hans?Georg Degen, Aurelia Pastor, Chantu R. Saha?Moller, Simon B. Schambony and Cong?Gui Zhao
Chapter four Organosulfonic and Sulfonimidic Peracids – New Oxidants for Diastereoselective and Enantioselective Oxidations of natural Substrates (pages 113–127): Manfred Schulz and Ralph Kluge
Chapter five Reactive Peroxo Compounds Generated in Situ from Hydrogen Peroxide: Kinetics and Catalytic program in Oxidation approaches (pages 128–138): Horst Elias and Stephane Vayssie
Chapter 6 Carbonyl O?Oxides and Dioxiranes – From Laboratory Curiosities to necessary Reagents (pages 139–156): ok. Block, W. Kappert, A. Kirschfeld, S. Muthusamy, ok. Schroeder, W. Sander, E. Kraka, C. Sosa and D. Cremer
Chapter 7 Formation of Dioxiranes and Singlet Molecular Oxygen through the Ketone?Catalyzed Decomposition of Peroxycarboxylic Acids (pages 157–176): Andreas Lange and Hans?Dieter Brauer
Chapter 1 Age and Age?Dependent ailments, a outcome of Lipid Peroxidation (pages 177–208): Gerhard Spiteller, Dieter Spiteller, Wolfgang Jira, Uwe Kie?ling, Angela Dudda, Michael Weisser, Stefan Hecht and Caroline Schwarz
Chapter 2 New Peroxycarboxylic Acids by way of Lipase Catalysis: practise and Oxidation homes (pages 209–231): Siegfried Warwel and Mark Rusch gen. Klaas
Chapter three Transition?Metal?Catalyzed Oxyfunctionalization of Catechol and Flavonol Derivatives (pages 232–248): Florian Schweppe, Holger Sirges, Matthias Pascaly, Mark Duda, Cetin Nazikkol, Werner Steinforth and Bernt Krebs
Chapter four Binding and Activation of Dioxygen through Biomimetic steel Complexes (pages 249–280): Ernst?G. Jager, Jutta Knaudt, Kerstin Schuhmann and Anka Guba
Chapter five Transition Metal?Catalyzed Stereoselective Synthesis of Functionalized Tetrahydrofurans (pages 281–300): Simone Drees, Marco Greb, Jens Hartung and Philipp Schmidt
Chapter 1 Metallosalen?Catalyzed uneven Oxygen?Transfer response: Dynamics of Salen Ligand Conformation (pages 301–319): Tsutomu Katsuki
Chapter 2 Transition?Metal Catalyzed Epoxidation of Unfunctionalized Alkenes (pages 320–340): Andreas Scheurer, Paul Mosset, Martina Spiegel and Rolf W. Saalfrank
Chapter three Peroxo Complexes of Molybdenum, Tungsten and Rhenium with part move lively Ligands: Catalysts for the Oxidation of Olefins and Aromatics via Hydrogen Peroxide and Bistrimethylsilyl Peroxide (pages 341–364): Carsten Jost, Gunter Wahl, Dirk Kleinhenz and Jorg Sundermeyer
Chapter four Kinetic answer through Jacobsen Epoxidation as a simple path to Podophyllotoxin Analoga (pages 365–380): Torsten Linker, Ulrike Engelhardt and Arunkanti Sarkar
Chapter five education of Optically lively Hydroperoxides and Their Use for Stereoselective Oxygen move (pages 381–405): Hans?Jurgen Hamann, Eugen Hoft and Jurgen Liebscher
Chapter 6 New Early Transition?Metal Complexes as Homogeneous Catalysts for Olefin Oxidation (pages 406–432): Wolfgang A. Herrmann, Jorg Fridgen and Joachim J. Haider
Chapter 7 Olefin Epoxidation Catalyzed via Molybdenum Peroxo Complexes: A Mechanistic learn (pages 433–453): Werner R. Thiel, Michael Barz, Holger Glas and Anna?Katharina Pleier
Chapter eight Oxidation Reactions in Perfluorinated Solvents (pages 454–468): Bodo Betzemeier and Paul Knochel
Chapter nine Transition?Metal Alkoxide?Catalyzed Oxidation of Phenols, Alcohols, and Amines with tert.?Butyl hydroperoxide (pages 469–493): Horst Adam, Karameli Khanbabaee, Karsten Krohn, Jochen Kupke, Hagen Rieger, Klaus Steingrover and Ingeborg Vinke
Chapter 10 Enantioselective Baeyer–Villiger Reactions and Sulfide Oxidations (pages 494–510): Carsten Bolm
Chapter eleven Chiral Pentacoordinated Manganese Complexes As Biomimetic Catalysts for uneven Epoxidations with Hydrogen Peroxide (pages 511–525): Albrecht Berkessel, Thomas Schwenkreis, Matthias Frauen?Kron, Adrian Steinmetz, Norbert Schatz and Jochen Prox
Chapter 12 Photocatalytic Activation of Oxygen through Iron(III)porphyrins (pages 526–541): Horst Hennig and Doritt Luppa
Chapter thirteen Oxidation and Oxygenation of Substituted Arenes with Alkyl Hydroperoxides or Dioxygen/Mediation through Schiff?Base Complexes (pages 542–566): Anton Rieker, Stefan Forster and Emerich Eichhorn
Chapter 1 the character of the Transition buildings for Oxygen Atom move from Peroxy Acids, Dioxiranes and Chiral Bis(silyl) Peroxides (pages 567–600): Robert D. Bach
Chapter 2 Mechanistic points of Transition?Metal?Catalyzed Olefin Epoxidation from Density practical reports (pages 601–619): Notker Rosch, Philip Gisdakis, Ilya V. Yudanov and Cristiana Di Valentin
Chapter three Near?UV Photolysis of Singlet Oxygen Generated through strength move from fragrant Molecules in Rare?Gas Matrices (pages 620–639): Murthy S. Gudipati, Robert Wagner, Martin Kalb and Andreas Klein
Chapter four Transition?Metal Ion Chemistry of Peroxides within the fuel section (pages 640–664): Detlef Schroder, Christoph A. Schalley and Helmut Schwarz

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Chem. Soc. 1928, 50, 568±571. ; GaÈnicke, K. Ber. dtsch. Chem. Ges. 1938, 71, 1430±1437. ; Flygare, H. Ber. dtsch. Chem. Ges. 1939, 72, 1799±1804. [27] Farmer, E. ; Sundralingam, A. J. Chem. Soc. 1942, 121±148. [28] cf. [1d], p. 116. ; Brunken, J. Liebigs Ann. Chem. 1928, 460, 225±235. [30] Fieser, L. F. Experientia, 1950, 6, 312. [31] Farmer, E. ; Koch, H. A. J. Chem. Soc. 1946, 10±13. [32] Swern, D. Organic Peroxides; Wiley Interscience: New York, 1970. ; Dean, P. H. Compt. rend. 1926, 182, 1440.

11] v. ; Villiger, V. Ber. dtsch. Chem. Ges. 1900, 33, 1569±1585. [12] a) v. ; Villiger, V. Ber. dtsch. Chem. Ges. 1899, 32, 3625±3633. ; Meunier, B. Eur. J. Org. Chem. 1999, 4, 737±750. [13] Wieland, H. Naturwiss. (Sonderheft) 1915, 3, 594±596. Citation: ªDie Untersuchungen von A. v. Baeyer uÈber Peroxide und Oxoniumverbindungen, die den Zeitraum von 1899±1915 umfassen, besonders die uÈber Hydroperoxide und die Carosche SaÈure, sind KabinettstuÈcke, nicht nur wegen der erreichten Erfolge, sondern namentlich in der Treffsicherheit und experimentellen Logik, womit die Resultate erreicht wurdenº.

Rev. 1992, 92, 1411±1456. ; Berkessel, A. Tetrahedron Lett. 1993, 34, 4785±4788. ; Katsuki, T. Synlett. 1994, 255.

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