By Jie Jack Li
In this 5th version of Jack Jie Li's seminal "Name Reactions", the writer has further twenty-seven new identify reactions to mirror the new advances in natural chemistry. As in prior variants, every one response is delineated by way of its specified step by step, electron-pushing mechanism and supplemented with the unique and the newest references, in particular from evaluate articles. Now with addition of many artificial purposes, this publication is not just an vital source for complicated undergraduate and graduate scholars, yet is usually an outstanding reference e-book for all natural chemists in either and academia.
Unlike different books on identify reactions in natural chemistry, identify Reactions, a suite of certain response Mechanisms and artificial functions specializes in the response mechanisms. It covers over 320 classical in addition to modern identify reactions.
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Additional resources for Name Reactions: A Collection of Detailed Reaction Mechanisms
Haddon, H. ; Balavoine, G. G. A. Synth. Commun. 1995, 25,629. 40 Boger pyridine synthesis Q H Hetero-Diels-Alder reaction Retro-Diels-Alder reaction, - N2 • ~ H~ o o • :B -N References 1. 2. 3. Boger, D. ; Panek, J. ; Meier, M. ]. Org. Chem. 1982, 47, 895. Boger, D. L. In Comprehensive Organic Synthesis Trost, B. , Eds, Pergamon, 1991, Vol. 5,451-512. ; Keyte, P. ; Paddon-Row, M. N. Tetrahedron 1992, 48, 7663. 41 Boord reaction Br R~R1 Zn dust • R~R 1 OEt Br Zn _R1 _ _ _ _ _ R~ - 'I OEt Oxidative addition EtO-ZnBr References 1.
J Chem. , Perkin Trans. 11997,2217. ; Herradon, B. SynJett2000, 509. ]. Org. Chem. 2000, 65,9143. ; Ohta, S. Heterocycles 2001,55,589. 37 Blaise reaction ~-Ketoesters from nitriles and a-haloesters using Zn. 1. Zn, THF, reflux R-CN + nucleophilic addition workup . - References 1. 2. 3. 4. 5. 6. 7. 8. 9. Blaise, E. E. C. R. Hebd. Seances Acad. Sci. 1901, 132,478. Kagan, H. -H. Bull. Soc. Chim. Fr. 1966, 1819. Hannick, S. ; Kishi, Y. J. Org. Chem. 1983, 48,3833. ; Kobayashi, K. Tetrahedron Lett. 1982, 23,1597.
8. ; Napieralski, B. 1893, 26,1903. ; Nagubandi, S. Heterocycles 1981,15, 165. Rozwadowska, M. D. ibid. 1994, 39, 903. ]. Org. Chem. 1996, 61,4062. ; Sato, Y. J Chem. , Perkin Trans. 11997,2217. ; Herradon, B. SynJett2000, 509. ]. Org. Chem. 2000, 65,9143. ; Ohta, S. Heterocycles 2001,55,589. 37 Blaise reaction ~-Ketoesters from nitriles and a-haloesters using Zn. 1. Zn, THF, reflux R-CN + nucleophilic addition workup . - References 1. 2. 3. 4. 5. 6. 7. 8. 9. Blaise, E. E. C. R. Hebd. Seances Acad.