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19, 219 (1979). 7. G. Lundquist, J. C. Huffman, and K. G. Caulton, J. Am. Chem. 8309 (1986). 7. p-HYDRIDO-TETRAKIS(ERT1ARY PHOSPH1NE)DIPLATINUM CATIONS Submitted by STANISLAV CHALOUPKA and LUICI M. VENANZF Checked by ROBERT L. COWAN and WILLIAM C. ' The M-H-M unit is conveniently described in terms of a three-center two-electron bonding scheme*analogous to that developed for boranes. One characteristic structural feature of the single M-H-M unit is its nonlinearity and M-H-M angles from loo" (see ref.
Properties The compound ReH,(PPh,), in an air-stable, white, microcrystalline solid that is soluble in dichloromethane, benzene, and THF. 6 in CD,CI,). Impurities can be removed by thorough washing with diethyl ether or by recrystallization from dichloromethane-methanol. The compound Re2(p-H),H,(PPh3), forms dark red crystals and bright red-orange powders; it is slightly soluble in diethyl ether, THF, benzene, carbon disulfide, and dichloromethane. The compound is most easily characterized by 'H NMR spectroscopy (see above) or by cyclic voltammetry.
Wasserman, J. Am. Chem. , 106, 451 (1984). (b) G. J. Kubas, R. R. Ryan, and D. Wrobleski, J. Am. Chem. , 108, 1339 (1986). (c) G. 1. Kubds. C. J. Unkefer, B. 1. Swanson, and E. Fukushima, J. Am. Chem. Soc.. 108, 7000 (1986). (d) G. J. Kubas, Acc. Chem. , 21, 120 (1988). 2. R. H. Crabtree and D. G. Hamilton, J. Am. Chem. Soc.. 108, 3124 (1986). 3. (a) H. J. Wasserman, G. J. Kubas, and R. R. Ryan, J . Am. Chem. , 108, 2294 (1986). (b) G. J. Kubds. Organometallk Syntheses, Vol. 3, R. B. King and J.