Inorganic Syntheses (Volume 23) by Stanley Kirschner

By Stanley Kirschner

The volumes during this carrying on with sequence supply a compilation of present thoughts and ideas in inorganic artificial chemistry. contains inorganic polymer syntheses and training of significant inorganic solids, syntheses utilized in the improvement of pharmacologically lively inorganic compounds, small-molecule coordination complexes, and similar compounds. additionally comprises worthwhile info on transition organometallic compounds together with species with metal-metal cluster molecules. All syntheses offered the following were established. learn more... content material: INORGANIC SYNTHESES quantity 23; CONTENTS; bankruptcy One ORGANOMETALLIC COMPOUNDS; bankruptcy COMPOUNDS OF organic curiosity; bankruptcy 3 STEREOISOMERS; bankruptcy 4 BRIDGE AND CLUSTER COMPOUNDS; bankruptcy 5 strange LIGANDS AND COMPOUNDS; precise possibility discover Appendix; Index of members; topic Index; formulation Index. summary: The volumes during this carrying on with sequence supply a compilation of present concepts and concepts in inorganic artificial chemistry. contains inorganic polymer syntheses and guidance of vital inorganic solids, syntheses utilized in the improvement of pharmacologically lively inorganic compounds, small-molecule coordination complexes, and comparable compounds. additionally comprises worthy details on transition organometallic compounds together with species with metal-metal cluster molecules. All syntheses provided the following were demonstrated

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1959) 1501. 232 F . A. Cotton and B. F . G . Johnson, Inorg. Chem. 6 (1967) 2 1 1 3 . 233 D. Hartley, P. A. Kilty and M. J. Ware, Chem. Communs. (1968) 4 9 3 . 246 TRANSITION METAL-METAL BONDS: D . L. KEPERT AND K. VRIEZE indicated a linear structure. The force to be about 1-6-1-7 mdynes/Â. The asymmetric trinuclear structure with constant ki of the O s = O s bond is 2-2 single bonds is 1 -7 mdynes/Â. constants of the metal-metal bonds were estimated 2 05 compound Os3(CO)io(OMe)2 probably has an 2 33 one O s = O s double b o n d (Fig.

Haag, Chem. Ber. 94 (1961) 312. 154 H. Behrens and W. Haag, Chem. Ber. 94 (1961) 320. 155 H. Behrens and J. Vogl, Chem. Ber. 96 (1963) 2220. 156 R. G. Hayter, / . Am. Chem. Soc. 88 (1966) 4376. 157 L. B. Handy, P. M. Treichel, L. F. Dahl and R. G. Hayter, J. Am. Chem. Soc. 88 (1966) 226. 158 W. Hieber, W. Beck and G. Braun, Angew. Chem. 72 (1960) 795. BONDS BETWEEN TRANSITION METAL ATOMS OF THE SAME ELEMENT 233 that the structural relationship between the two isomeric forms is similar to those of 159 C o 2( C O ) 8 « > .

VRIEZE negative charge is delocalized on all four metal atoms. The possible existence of HRe4(CO)7 6 181 and H 2R e 4 ( C O ) i 6 was m e n t i o n e d . 18 Further hydrides which were confirmed by mass spectrometry are HRe3(CO)i4 ° » 183 and the dark red HMn3(CO)io(BH3)2, which was obtained as a by-product of the synthesis 1 8 4 of H 3M n 3( C O ) i 2 . The structure of H R e 3 ( C O ) i 4 is very likely similar to that of 1 8 5 H R e 2M n ( C O ) i 4 . The structure of H M n 3 ( C O ) i 0 ( B H 3 ) 2 is shown in Fig.

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