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Additional resources for Inorganic Reactions and Methods, Formation of Bonds to O, S, Se, Te, Po (Part 2) (Zuckerman: Inorganic Reactions and Methods)
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7. 8. 9. 10. 1 By Oxidation of the Metals and Their Complexes Metallic Cu, Ag, Au, and Hg are all efficient heterogeneous catalysts for the decomposition of H 2 0 2 ;Zn and Cd are slightly less so. Consequently there have been few investigations directed toward stoichiometric reaction of these metals with H 2 0 2 and organic peroxides. Metallic Zn is converted to ZnO upon treatment with neutral H 2 0 2 . Dissolution of Cu, Ag, and Hg yields aquocations of Cu(II), Ag(I), and Hg(I1); reaction occurs in 30% H 2 0 2acidified with dilute H2S04 (Cu, Ag) and HOAc (Cu, Ag, Hg)’.
64,99 (1964); W. H. Watson, Inorg. , 8, 1879 (1969). 4. D. S . Brown, J. D. Lee, B. G. A. Melsum, J . Chem. , Chem. , 852 (1968). 5. R. L. Carlin, R. Rottman, M. Dankleff, J. 0. Edwards, Inorg. , 1, 182 (1962). 6. D. M. L. Goodgame, F. A. Cotton, J . Chem. , 2298 (1961). 7. R. A. Jorge, C. Airoldi, A. P. Chagas, J . Chem. , 1102 (1978). 8. N. M. Karayannis, C. M. Mikulski, L. L. Pytlewski, Inorg. , 5, 69 (1971). 9. D. L. Kepert, D. Taylor, A. H. White, J . Chem. , 1658 (1973). 10. W. L. Reynolds, Prog.
3. T. G. Brilkina, V. A. Shushunov, Reactions of Organometallic Compounds with Oxygen and Peroxides, Iliffe, London, 1969. 4. G. A. Razuvaev, V. A. Shushunov, V. A. Dodonov, T. G. Brilkina, Organic Peroxides, Vol. 3, D. , Wiley-Interscience, New York, 1972, p. 141. 2 By Oxidation of the Ligands Coordinated to the Metals Phthalocyanines of Cu, Ag, Zn, and Hg are oxidized to the aquo or sulfato complexes, phthalimide, and ammonium ion by H 2 0 z in 17 M HzSO4l. (M. T. POPE) 1. B. D. Berezin, G. V.