Inorganic Molecules by K. Kuchitsu, E. Hirota, D. A. Ramsay, J. Vogt, N. Vogt

By K. Kuchitsu, E. Hirota, D. A. Ramsay, J. Vogt, N. Vogt (auth.), K. Kuchitsu, M. Tanimoto, N. Vogt (eds.)

Volume II/28 is a supplemented and revised variation of the previous volumes II/7, II/15, II/21, II/23 and II/25, containing brand new details at the geometric parameters (internuclear distances, bond angles, dihedral angles of inner rotation etc.) of unfastened inorganic and natural polyatomic molecules. All experimental tools for the decision of quantitative structural facts of unfastened molecules were thought of: microwave, infrared, Raman, digital and photoelectron spectroscopy in addition to electron diffraction. the knowledge acquired through those tools were severely evaluated and compiled. they're provided individually for every molecule, including a computer-drawn schematic determine of the constitution and the unique literature.

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A 103 (1999) 1644. 3(13) The ED investigation was coupled with a quadrupole mass spectrometric experiment. The nozzle temperature was 360 K. a ) Estimated total errors. ) Effective dihedral angle of the four-membered ring between the Br(b)AlBr(b) planes due to the large-amplitude puckering vibration. : Chem. Phys. Lett. 257 (1996) 321. 1(31) θα No monomeric species of AlCl3 molecule were detected in the vapor. The effect of the largeamplitude ring puckering mode on the interatomic distances was handled by a dynamic model composed of a set of pseudoconformers.

Phys. 2 (2000) 3943. 1983(10) C∞v (effective symmetry class) (large-amplitude motion) Ar · AuCl The complex is linear and is relatively rigid in the ground vibrational state. 5 N m–1. Au bond is weakly covalent. a ) Uncertainties were not estimated in the original paper. : J. Am. Chem. Soc. 122 (2000) 6100. Au stretching wavenumber estimated as ca. 0 N m–1. Au bond is weakly covalent. a ) Uncertainty was not estimated in the original paper. ) Assumed. : Phys. Chem. Chem. Phys. 2 (2000) 3943. 7 × 10–20 J rad–2, respectively.

The Ar…Cu stretching wavenumber is estimated to be ca. 200 cm–1. a ) Estimated standard errors. ) By a double substitution method. Uncertainties were not estimated in the original paper. : J. Chem. Phys. 112 (2000) 9363. 164 N m–1. a ) Uncertainties were not estimated in the original paper. ) Average angle between the a inertial axis and the HCl molecular axis. : Chem. Phys. Lett. 291 (1998) 190.

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