Host-Guest-Systems Based on Nanoporous Crystals by Franco Laeri, Ferdi Schüth, Ulrich Simon, Michael Wark

By Franco Laeri, Ferdi Schüth, Ulrich Simon, Michael Wark

Curiosity in nanoporous crystals as host-guest platforms has risen dramatically during the last few years, such that this interesting category of drugs now performs an immense position not just in fabric sciences, but additionally in several different disciplines, corresponding to natural or supramolecular chemistry. With their particular features, nanoporous crystals provide a variety of attainable functions: they're used as molecular sieves or membranes in addition to catalytic converters. This paintings provides the first actual assessment of this fascinating box. Readers will locate every thing they should learn about those strange fabrics, with all their many attributes:Synthesis of host-guest platforms Description of the structural and dynamic features digital and optical features of the fabrics attainable purposes. An essential reference for fabrics scientists in addition to for catalytic and inorganic chemists, and all these operating within the box.

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1995, 368, 369. P. Behrens, G. C. Freyhardt, Angew. Chem. 1995, 107, 2895; Angew. Chem. Int. Ed. Engl. 1995, 34, 2680. G. van de Goor, B. Lindlar, J. Felsche, P. Behrens, Chem. Commun. 1995, 2559. M. Schneider, P. Behrens, J. Mol. Graphics 1996, 14, 381. G. van de Goor, K. Hoffmann, ¨ th, S. Kallus, F. Marlow, F. Schu P. Behrenst, Adv. Mater. 1996, 8, 65. C. Freyhardt, M. F. J. E. Davis, Nature 1996, 381, 295. J. Balkus, M. G. Gabrielov, Stud. Surf. Sci. Catal. 1997, 105, 415. P. Behrens, Ch. Panz, V.

H. Gies, B. Marler, Zeolites, 1992, 12, 42. H. Gies, B. Marler, U. G. Karge, J. ), Vol. 1: Synthesis, Springer, Berlin 1998, p. 35. J. Balkus, S. Shepelev, Microporous Mater. 1993, 1, 383. J. G. Gabrielov, N. Sandler, Mater. Res. Soc. Symp. Proc. 1995, 368, 369. P. Behrens, G. C. Freyhardt, Angew. Chem. 1995, 107, 2895; Angew. Chem. Int. Ed. Engl. 1995, 34, 2680. G. van de Goor, B. Lindlar, J. Felsche, P. Behrens, Chem. Commun. 1995, 2559. M. Schneider, P. Behrens, J. Mol. Graphics 1996, 14, 381.

In further investigations it became clear that is was not the intact dye molecules that cause the luminescence, but either a by-product remaining from the synthesis of the azo surfactants or a product of the possible destruction of these molecules, which might have taken place during the AlPO4 -5 synthesis. Determining the true identity of the luminescent species is difficult and has not yet been achieved. 5 Easily Crystallizing Inorganic Frameworks: Zincophosphates tals exhibit luminescence). Traces of luminescent species were isolated from the synthesis mixtures of the azo surfactants and characterized by luminescence spectroscopy, and there appears to be some resemblance to the luminescence spectra of those AlPO4 -5 crystals.

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