Endohedral metallofullerenes: fullerenes with metal inside by Hisanori Shinohara, Nikos Tagmatarchis, Sir Harold Kroto

By Hisanori Shinohara, Nikos Tagmatarchis, Sir Harold Kroto

Endohedral Metallofullerenes: Fullerenes with steel Inside provides a complete survey of the present country of data on endohedral metallofullerenes, from training to functionalization, reactivity and purposes. Following a quick old assessment, the e-book describes equipment for synthesis, extraction, separation and purification, and offers an perception into the molecular and crystal buildings. next chapters speak about a number of different types of endohedral metallofullerenes in keeping with the encapsulated species, together with carbides, nitrides, sulphides, oxides, non-metal and non-IPR endohedral metallofullerenes, via scanning tunneling microscopy reviews and the exam of digital, vibrational, magnetic and optical houses. The ebook concludes with chapters addressing the chemical functionalization of endohedral metallofullerenes, and purposes starting from sun cells to biomedicine.

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They found that the polymerization of Li@C60 with C60 prevents the accurate determination of the structure and physical properties of the polymer. 34 Endohedral Metallofullerenes Aoyagi et al. reported the bulk synthesis of Li@C60 using a reported plasma method [99] modified for the synthesis of Li@C60 and the complete isolation of a [Li@C60] salt, together with the molecular and crystal structure determination of a [Li@C60](SbCl6) [100]. Ever since Campbell and co‐workers’ original synthesis of Li@C60, it had not been possible to separate Li@C60 from the pristine C60 due to a strong charge transfer interaction between them.

3 La@C82 Metallofullerene The La@C82 metallofullerene is one of the first endohedral metallofullerenes that was macroscopically produced and solvent extracted [1]. Suematsu et al. [54] first reported the crystal structure of La@C82 precipitated from CS2 solution via synchrotron X‐ray powder diffraction. 5. The crystal has a cubic structure. The results suggest a molecular alignment in the unit cell, in which the molecules align in the [111] direction with the molecular axis orienting in the same [111] direction.

References [1] Haufler R E, Chai Y, Chibante L P F et al. 1991 Cluster‐Assembled Materials, Vol. 206, eds R S Averback, J Bernhoc and D L Nelson (Pittsburgh, PA: Materials Research Society), pp. 627–637 [2] Chai Y, Guo T, Jin C et al. 1991 Fullerenes with metals inside J. Phys. Chem. 95 7564 [3] Ying Z C, Jin C, Hettich R L et al. 1994 Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Vol. 1, eds K Kadish and R Ruoff (Pennington, NJ: Electrochemical Society), pp.

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