Critical Stability Constants: Volume 2: Amines by Arthur Martell, Robert M. Smith

By Arthur Martell, Robert M. Smith

Over the previous fifteen years the fee on Equilibrium information of the Analytical department of the Inter­ nationwide Union of natural and utilized Chemistry has been sponsoring a noncritical compilation of steel complicated formation constants and similar equilibrium constants. This paintings was once wide in scope and led to the e-book of 2 huge volumes of balance Constants by way of the Chemical Society (London). the 1st quantity, edited via L. G. Sillen (for inorganic ligands) and by way of A. E. Martell (for natural ligands), was once released in 1964 and lined the literature via 1962. the second one quantity, subtitled complement No. 1, edited through L. G. Sillen and E. Hogfeldt (for inorganic ligands) and through A. E. Martell and R. M. Smith (for natural ligands), used to be released in 1971 and coated the literature as much as 1969. those huge compilations tried to hide all papers within the box with regards to steel complicated equi­ libria (heats, entropies, and unfastened energies). because it was once the coverage of the fee in the course of that interval to prevent judgements about the caliber and reliability of the printed paintings, the compilation could usually comprise from ten to 20 values for a unmarried equilibrium consistent. in lots of instances the values could fluctuate by way of one or perhaps orders of value, therefore problematical readers who desired to use the information with no doing the wide literature examine essential to make sure the right kind worth of the consistent in question.

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L ML. 7) Bibliography: H+ 37N,41GH,60MC,66HP,67HP 2 Ni + 60MC Other reference: 56DR A. 09 Bibliography: 73NA L II. 7 33 A. 3 3 2 MLzll--1. H 11. L 2 MLzlM. 1 Bibliography: H+ 65CM,66HP,69PPH Ni 2+_Pb2+ 69PPH Other reference: 55LM (24 ) II. 5 Ag+ 51G 2 Cd + 56BF 35 A. 0 Other reference: 541 (2) II. 1 h 250, 1. 4 6 -10. 95 f ±0. 4; A. OH Cr 3+ }1L 2 /MOHL 2 . 0 Log K 25°, 0 LIS 25° ! l 11. 64 -11. L 3 MLzlMOHL 2 . L 2 3 MLi M. l5 i 11. 1; 38 II. 1 Bibliography: Cu+ 6lJW H+ 45BA,4BBN,52BM,52EP,52H,52SA,54DS, 56WM, 57MC, 61CP, 63NMa,64FB,66PCI,67HW, Ag+ 52SA 67VA,69HG,70FR,71HBM CH 3Hg+ 65SS Mg 2+ 41B Pd Z+ 6BRJ Cr 2+ 57PB Pt 2+ 61GG Mn 2+ 41B,60CP,74MM Zn 2+ 45BA,53SPa,55NM,59MB,60CP,69PS,70FR, Fe 2+ 41B,60CP 7lGS,74MM C0 2+ 41B,50E,60CP,69PS,71GS,72NMa 2 Cd + 45BA,45CM,53SP, 54DS,55CH, 58BB,64SM, Ni 2+ 41B,45CM,50E,52BMa,52H,54DS,55PB, 73CV,73MB 59MB, 60CP, 63Ca,65NKK, 67HWa, 68FV, 68PK, 2 Hg + 50B, 55NR, 56WM,61RM, 66PCI 68PS,70FR,71GS,74MM Pb 2+ 69IM,74K Cu 2+ 45CM,48BN,52BMa,53SPa,54DS,55CH,55JR, 55PB,57MC,59MB,63NMa,64SM,67HWa,67PS, Other references: 28J,35BW, 36BW,4BMM, 49LO, 68PK,70FR,70GS,71HBM,71SSb,72BFa SODL,54BM,56M,57B,57V,61ALa,61BS,61KPa, 63KV,640M,66PS,67LK,67SP,67SS,6BFD, 3 Cr + 57H 69MI,69VS,70MAc,71SSb,72HJ,730I,73ZT C0 3+ 41B,52BR A.

OO 6S 25°, 0 49LO,50DL, 50E,7301 (_6)c 40 II. 24 2 ML 2/M. 32)a a Optical isometism not stated. 1 A. 2l a D- and DL-isomers gave the same value. Bibliography: H+ 53BM,70AB Ni 2+,Cu 2+ 54BC,70AB L II. L 2 (meso-2,3-buty1enediamine) Log K 25°! 46 Log K 25°! 15 Bibliography: H+ 53BM,63L,70AB Mn2+,zn 2+ 63L Ni 2+,Cu 2+ 54BC,70AB L A. L 2 :CS 25°, 0 a Optical isomerism not stated. 65 HL/H. 92 Bibliography: H+ 53BM,63L Zn 2+ Ni 2+ Cu 2+ 54BC,63L Other reference: 54BC 63L 68Pb 44 II. 30) L 45 A. L 2 ML 2/MOHL 2 .

5 Ag+ 51G 2 Cd + 56BF 35 A. 0 Other reference: 541 (2) II. 1 h 250, 1. 4 6 -10. 95 f ±0. 4; A. OH Cr 3+ }1L 2 /MOHL 2 . 0 Log K 25°, 0 LIS 25° ! l 11. 64 -11. L 3 MLzlMOHL 2 . L 2 3 MLi M. l5 i 11. 1; 38 II. 1 Bibliography: Cu+ 6lJW H+ 45BA,4BBN,52BM,52EP,52H,52SA,54DS, 56WM, 57MC, 61CP, 63NMa,64FB,66PCI,67HW, Ag+ 52SA 67VA,69HG,70FR,71HBM CH 3Hg+ 65SS Mg 2+ 41B Pd Z+ 6BRJ Cr 2+ 57PB Pt 2+ 61GG Mn 2+ 41B,60CP,74MM Zn 2+ 45BA,53SPa,55NM,59MB,60CP,69PS,70FR, Fe 2+ 41B,60CP 7lGS,74MM C0 2+ 41B,50E,60CP,69PS,71GS,72NMa 2 Cd + 45BA,45CM,53SP, 54DS,55CH, 58BB,64SM, Ni 2+ 41B,45CM,50E,52BMa,52H,54DS,55PB, 73CV,73MB 59MB, 60CP, 63Ca,65NKK, 67HWa, 68FV, 68PK, 2 Hg + 50B, 55NR, 56WM,61RM, 66PCI 68PS,70FR,71GS,74MM Pb 2+ 69IM,74K Cu 2+ 45CM,48BN,52BMa,53SPa,54DS,55CH,55JR, 55PB,57MC,59MB,63NMa,64SM,67HWa,67PS, Other references: 28J,35BW, 36BW,4BMM, 49LO, 68PK,70FR,70GS,71HBM,71SSb,72BFa SODL,54BM,56M,57B,57V,61ALa,61BS,61KPa, 63KV,640M,66PS,67LK,67SP,67SS,6BFD, 3 Cr + 57H 69MI,69VS,70MAc,71SSb,72HJ,730I,73ZT C0 3+ 41B,52BR A.

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