Critical Stability Constants: Second Supplement by Arthur E. Martell, Robert M. Smith

By Arthur E. Martell, Robert M. Smith

Over the previous twenty 5 years the fee on Equilibrium info of the Analytical department of the foreign Union of natural and utilized Chemistry has been sponsoring a noncritical compilation of steel complicated formation constants and comparable equilibrium constants. This paintings was once huge in scope and ended in booklet of 2 huge volumes of balance Constants by means of the Chemical Society (London). the 1st quantity, edited via L. G. Sillen (for inorganic ligands) and by way of A. E. Martell (for natural ligands), was once released in 1964 and lined the literature via 1962. the second one quantity, subtitled complement No. 1, edited by means of L. G. Sillen and E. Hogfeldt (for inorganic ligands), and A. E. Martell and R. M. Smith (for natural ligands), used to be released in 1971 and coated the literature as much as 1969. those huge compilations tried to hide all papers within the box regarding steel advanced equilibria (heats, entropies, and loose energies). so much lately a noncritical compilation of natural ligands through D. D. Perrin (Pergamon Press) prolonged insurance of the literature via 1973 and the same quantity for inorganic ligands by way of E. Hogfeldt coated via 1974. because it used to be the coverage of the fee in the course of that interval to prevent judgements in regards to the caliber and reliability of the broadcast paintings, th~ compilation might often include from ten to 20 values for a unmarried equilibrium constant.

Show description

Read or Download Critical Stability Constants: Second Supplement PDF

Similar inorganic books

Spectroscopic Properties of Inorganic and Organometallic Compounds: v. 6: A Review of Chemical Literature (Specialist Periodical Reports)

Spectroscopic houses of Inorganic and Organometallic Compounds offers a special resource of knowledge on an immense zone of chemistry. Divided into sections frequently in keeping with the actual spectroscopic strategy used, insurance in every one quantity comprises: NMR (with connection with stereochemistry, dynamic structures, paramagnetic complexes, reliable kingdom NMR and teams 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of major team and transition aspect compounds and coordinated ligands; and electron diffraction.

Industrial Chemistry: New Applications, Processes and Systems

This assortment provides to the reader a vast spectrum of chapters within the a number of branches of commercial chemistry, which display key advancements in those swiftly altering fields.

Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution

Ionisation Constants of Inorganic Acids and Bases in Aqueous resolution, moment version presents a compilation of tables that summarize correct facts recorded within the literature as much as the top of 1980 for the ionization constants of inorganic acids and bases in aqueous answer. This publication comprises references to acidity capabilities for powerful acids and bases, in addition to information about the formation of polynuclear species.

Extra info for Critical Stability Constants: Second Supplement

Sample text

2 (45) A. L Log K 25°. 2lb Log K 25 °. 1. 0 Log K 25°. 0 Mt 25°. S 25°. HL 2/MHL. 22) Log K Log K Log K 0 25°. 0 25°. 1 °. H 7. 43 (1. 9) (1. H (1. 9)n-o. 2 (1. H Log K 2s•. 1 Log K 2s•. 8 Log K 2s·. 93 ML 2 /MOH! 0 10. HL 5. 51 MHL 2/ML 2 . H 6. 99n 7. 63 ML 2 /MOHL 2 . H 10. 46 11. lS; Yo- and DL-isomers have about the same value. H DL-2-Mercaptohistidine HzL Log K zs·. H zs·. l; woptical isomerism not given. 6S zs·. 1 (10) (6) A. 426) ~H Log K Log K Log K 25". 1 25". o 25•. 5 25•. 2 M(HL) 2;M.

7) (1. 35)x (1. 16)x Ag+ 81PSK,84TS HL A. l, p. 33c 1. 99 1. 04 4. HL M(HL) 2/M. 5 -11. 7 26 II. H Log K 25°. 35 25°. HL M(HL) 2;M. 87 1. HL M(HL) 2/M. 64) (7. L Log K 20·. 03 Log K 37". 05 (1. 73 4. 6 9 20 -7 A. PRIMARY AMINES 27 Cystine (continued) Metal ion zn 2+ Equilibrium Log K 20". HL M(HL) z~M. HL c 7H14o4N2 s 2 Metal ion ~ Co 2+ Log K 25". 72 7. 0 (1. 42 (1. 9) (1. H Bibliography: Log K 37". 1 (2) (2) (6) 28 II. AMINOCARBOXYLIC ACIDS Dienkolic acid (continued) Metal Eguilibriurn Log K 25°.

H 2s·. 4) -5. HL M(HL) 2/M. HL M(HL) 2/M. HL M(HL) 2/M. (HL) 2 M(HL) 2/MHL 2 . HL M(HL) 2/M. 1 24 9 A. HL M(HL) 2/M. HL M(HL) 2/M. HL M(HL) 2/M. (HL) 2 M(HL) 3;M. H MH2L 3/MHL 3 . 01 M(HL) 2;M. 37)x M(HL) 2;M. HL M(HL) 2/M. 43 Log K 25". 6 12 23 22 14 II. 14 AMINOCARBOXYLIC ACIDS Tyrosine (continued) Metal ion Co 2+ Ni 2+ cu 2+ zn 2+ Eguilibrium Log K 25°. 0 Log K 25°. 0 Log K 25° 0 0 6H 6S 25°. 1 25°. HL M(HL) 2/M. (HL) 2 M(HL) 3/M. H MH2 L3/MHL 3 . HL M(HL) 2/M. (HL) 2 M(HL) 3/M. H MH 2L;MHL 3 .

Download PDF sample

Rated 4.11 of 5 – based on 44 votes