By Armando J. L. Pombeiro
A modern compilation of contemporary achievements in organometallic chemistry
The prestigious foreign convention on Organometallic Chemistry (ICOMC) used to be introduced in 1963, delivering a discussion board for researchers from around the globe to percentage their findings and discover new paths to improve our wisdom and alertness of organometallic chemistry. The twenty fifth ICOMC, held in Lisbon in 2012, accrued greater than 1,200 members from fifty four nations. This quantity celebrates the twenty fifth Silver variation and the fiftieth Gold 12 months of the ICOMC.
Featuring contributions from invited twenty fifth ICOMC audio system, Advances in Organometallic Chemistry and Catalysis highlights fresh achievements and new and rising components of study within the box. Its seven sections cover:
- Activation and Functionalization of Carbon unmarried Bonds and Small Molecules
- Organometallic Synthesis and Catalysis
- Organometallic Polymerization Catalysis
- Organometallic Polymers and Materials
- Organometallic Chemistry and Sustainable Energy
- Bioorganometallic Chemistry
- Organometallic Electrochemistry
Chapters talk about primary underlying thoughts, provide illustrative examples and circumstances, and discover destiny avenues for persevered examine. Readers will become aware of uncomplicated ideas and homes of organometallic compounds, response mechanisms, and particular descriptions of present purposes. jointly, those chapters underscore the flexibility, richness, and strength of recent organometallic chemistry, together with its interrelationships with different medical disciplines.
All the contributions are greatly referenced, delivering a gateway to crucial unique study papers and reports in organometallic chemistry. featuring a modern knowing of organometallic chemistry and its many purposes, Advances in Organometallic Chemistry and Catalysis is usually recommended for all researchers within the box, from scholars to complicated investigators.
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Additional info for Advances in Organometallic Chemistry and Catalysis: The Silver / Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book
Chem. 2011, 696 , 1310 Silva T. F. ; Luzyanin, K. ; Kirillova, M. ; Guedes da Silva, M. F. ; Martins, L. M. ; Pombeiro, A. J. L. Adv. Synth. , 2010, 352 , 171. Silva, T. F. ; Mishra, G. ; Guedes da Silva, M. F. ; Martins, L. M. D. R. ; Pombeiro, A. J. L. Dalton Trans. 2009, 9207 Silva, T. S. ; Alegria, E. C. B. ; Martins, L. M. D. R. ; Pombeiro, A. J. L.. Adv. Synth. Catal. 2008, 350 , 706. Kopylovich, M. ; Gajewska, M. ; Mahmudov, K. ; Kirillova, M. ; Figiel, P. ; Guedes da Silva, M. F. ; Pombeiro, A.
41] and included pyrazinecarboxylic acid (PCAH) as a promoter. As indicated by radical trap experiments, various types of selectivity (regio-, bond-, and stereo-selectivity), and kinetic and theoretical studies [18–24, 27, 29, 33–40], these peroxidative oxidations of alkanes occur via radical mechanisms. They are believed to proceed via free hydroxyl radical (HO• ) that acts as an H-abstractor from the alkane RH to yield the corresponding alkyl radical R• . Fast reaction of R• with O2 generates the alkylperoxyl radical ROO• , which, following known pathways [38, 39, and references therein], lead to the formation of the ﬁnal alcohol (ROH) and the corresponding ketone via the alkylperoxide ROOH.
Shul’pin, G. B. Mini-rev. Org. Chem. 2009, 6 , 95. 7. Diaz-Requejo, M. ; Perez, P. J. Chem. Rev. 2008, 108 , 3379. 8. ; Tolman, W. B. Nature 2008, 455 , 333. 9. Pombeiro, A. J. L. , Pessoa, J. , Crans, D. ; American Chemical Society Symposium Series 974; American Chemical Society, Washington DC, 2007; Chapter 4, pp 51–60. 10. Pombeiro, A. J. L. ; Education in Advanced Chemistry Series 9; PoznanWroclaw, 2005; pp 93–113. 11. ; Tilset, M. Chem. Rev. 2005, 105 , 2471; (b) Crabtree, R. H. J. Organomet.